SN1 w/rearrangement [hydride shift]

SN1 Hydride Shift Rearrangement SN1 rearrangement [hydride shift] Definition: The 1,2-hydride shifts can occur during the reactions if an unstable carbocations is formed next to a tertiary carbon. SN1 Hydride Shift Explained: We have already…

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SN1 with rearrangement [alkyl shift]

SN1 w/ rearrangement [alkyl shift] SN1 w/rearrangement [alkyl shift] Definition: The 1,2-alkyl shift can occur during the substitution reactions if an unstable carbocation is formed adjacent to a quaternary carbon. SN1 rearrangement [alkyl shift] Explained:…

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Ether formation [ROH]

Ether formation [ROH] Ether formation (ROH) Definition: Alkyl halides can be converted to ethers when dissolved in alcohol solvents through an SN1 reaction. Ether formation (ROH) Explained: The SN1 mechanism is a stepwise process in…

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Alkyl iodide formation [HI]

Alkyl iodide formation [HI] Alkyl iodide formation (HI) Definition: Tertiary alcohol can be converted to tertiary alkyl iodide with hydroiodic acid (HI). Alkyl iodide formation (HI) Explained: This reaction proceeds…

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Alkyl chloride formation [HCl]

Alkyl chloride formation [HCl] Alkyl chloride formation (HCl) Definition: Treatment of tertiary alcohols with HCl leads to the formation of tertiary alkyl chlorides. Alkyl chloride formation (HCl) Explained: The order…

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Alcohol formation [H2O]

Alcohol formation [H2O] Alcohol formation (H2O) Definition: Alkyl halides will react with water to form alcohols through an SN1 mechanism. Alcohol formation (H2O) Explained: Unimolecular nucleophilic substitution abbreviated SN1, in which Unimolecular or number 1 indicates that only…

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Alcohol formation [ether cleavage]

Alcohol formation [ether cleavage] Alcohol formation [ether cleavage] Definition: When treated with acid, ether od tertiary, benzylic, or allilyc carbons can fragment to give a carbocation, which is then trapped by a nucleophile in an…

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